全文获取类型
收费全文 | 1477篇 |
免费 | 214篇 |
国内免费 | 1031篇 |
专业分类
安全科学 | 59篇 |
废物处理 | 37篇 |
环保管理 | 108篇 |
综合类 | 1657篇 |
基础理论 | 344篇 |
污染及防治 | 308篇 |
评价与监测 | 168篇 |
社会与环境 | 41篇 |
出版年
2024年 | 6篇 |
2023年 | 47篇 |
2022年 | 102篇 |
2021年 | 129篇 |
2020年 | 126篇 |
2019年 | 122篇 |
2018年 | 100篇 |
2017年 | 117篇 |
2016年 | 138篇 |
2015年 | 153篇 |
2014年 | 135篇 |
2013年 | 171篇 |
2012年 | 141篇 |
2011年 | 159篇 |
2010年 | 141篇 |
2009年 | 126篇 |
2008年 | 123篇 |
2007年 | 97篇 |
2006年 | 119篇 |
2005年 | 70篇 |
2004年 | 56篇 |
2003年 | 79篇 |
2002年 | 39篇 |
2001年 | 38篇 |
2000年 | 34篇 |
1999年 | 27篇 |
1998年 | 24篇 |
1997年 | 21篇 |
1996年 | 22篇 |
1995年 | 21篇 |
1994年 | 11篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 10篇 |
1990年 | 1篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1981年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有2722条查询结果,搜索用时 78 毫秒
71.
Fenton法处理垃圾渗滤液MBR-NF浓缩液 总被引:1,自引:0,他引:1
采用Fenton法处理MBR-NF浓缩液,考察了FeSO4·7H2O投加量、n(H2O2)/n(Fe2+)投加比、初始pH对渗滤液MBR-NF浓缩液处理效果的影响,并在最佳实验条件下,探讨浓缩液富里酸(FA)、亲水性有机物(HyI)组分在Fenton氧化前后组成的变化。研究结果表明,在FeSO4·7H2O投加量为0.055 mol/L、n(H2O2)/n(Fe2+)投加比为4、初始pH为7.58时,对COD、腐植酸(UV254)、色度(CN)的去除率分别为79.6%、93.7%和97.8%。Fenton氧化后,浓缩液中有机物组分含量发生了较大变化,腐植酸含量下降,HyI成为渗滤液溶解性有机物主要成分。紫外-可见光谱表明,Fenton法对FA去除效果较好,而对HyI氧化效果较差;傅立叶红外光谱显示,经Fenton氧化后,FA的结构发生了明显变化,而HyI则变化不明显。 相似文献
72.
针对无锡地区2013年11月6—13日经历的灰霾污染和清洁过程,采用地基遥感激光雷达对空气中的气溶胶颗粒物垂直分布进行垂直探测,发现污染时段气溶胶颗粒物主要积聚在1.8 km以下,消光系数的日均值统计表明,从近地面至高空1.5 km,颗粒物产生的峰值消光系数稳定在0.2 km~(-1);而清洁时段,由于垂直扩散条件改善,颗粒物随高度增加明显减少,1.5 km处的消光系数不足0.05 km~(-1)。同时发现污染时段中,近地面PM_(10)、PM_(2.5)、碳黑(BC)的平均浓度分别是清洁时段的2.48、2.76、3.66倍;大气氧化剂(O3和NO_x的总和)平均值水平是清洁时段的1.73倍。气象条件分析发现,锋面的移动使大气水平、垂直对流运动加剧,污染物得以迅速扩散,空气质量转好,这也是此次污染清除的主要原因。 相似文献
73.
Kelly K. Moran Julie D. Jastrow 《Environmental pollution (Barking, Essex : 1987)》2010,158(4):1088-1094
The potential for storing additional C in U.S. Corn Belt soils - to offset rising atmospheric [CO2] - is large. Long-term cultivation has depleted substantial soil organic matter (SOM) stocks that once existed in the region's native ecosystems. In central Illinois, free-air CO2 enrichment technology was used to investigate the effects of elevated [CO2] on SOM pools in a conservation tilled corn-soybean rotation. After 5 and 6 y of CO2 enrichment, we investigated the distribution of C and N among soil fractions with varying ability to protect SOM from rapid decomposition. None of the isolated C or N pools, or bulk-soil C or N, was affected by CO2 treatment. However, the site has lost soil C and N, largely from unprotected pools, regardless of CO2 treatment since the experiment began. These findings suggest management practices have affected soil C and N stocks and dynamics more than the increased inputs from CO2-stimulated photosynthesis. 相似文献
74.
石化企业应急救援能力评估研究 总被引:4,自引:0,他引:4
随着应急能力建设逐步引起我国各行各业的重视,越来越多的石化企业己经开始加大对应急能力建设工作的力度,以尽可能的减少生产事故所带来的损失。作为石化企业应急能力建设的重要组成部分,石化企业生产事故应急救援能力的评价研究具有十分重要的理论和实践意义。本文首先对石化企业生产及事故特点和石化企业应急能力进行了详细的剖析,初步构建了石化企业生产事故应急能力评价指标体系。进而根据物元可拓性理论,结合石化企业的实际情况,运用可拓评判方法建立石化企业应急救援能力综合评判的模型,给出了评价步骤,最终确定企业的生产事故应急能力等级,从而对企业持续改进应急能力建设提供一定的参考。研究结果表明,该方法可应用于多层次的工程风险评价问题,从而为石化工程项目风险管理提供了一种有效的分析方法。 相似文献
75.
76.
77.
Sebastian Weissenberger Marc Lucotte Stéphane Houel Nicolas Soumis Éric Duchemin René Canuel 《Ecological modelling》2010,221(4):610-620
A mechanistic semi-empirical carbon cycle model of the La Grande reservoir complex in northern Quebec, Canada was conceived in order to investigate the climate impact of such a large alteration of the continental water cycle. The model includes inputs from the drainage basin, organic matter release from flooded soils, CO2 emissions across the water-atmosphere interface and sedimentation. Most input data stems from previous research by our group on those ecosystems. The model includes the seven reservoirs of the La Grande complex and was run for periods of 50 and 100 years. Terrigeneous dissolved, particulate and suspended soil carbon fluxes and concentrations were computed. Over 100 years, 31.3 × 1012 g C are released from flooded soils, equivalent to 28-29% of inputs from the drainage basin. 40-74% of dissolved organic carbon is mineralized. CO2 fluxes over 100 years are 50.5-79.8 × 1012 g C, 46.4-67.9 × 1012 g C more than in the absence of reservoirs. The increase in mineralization of organic matter and in CO2 emissions is a result of the increase in cumulated water residence time due to the creation of the reservoirs. Changes in other carbon sinks and sources likely offset a part of this additional carbon flux to the atmosphere. In the first years following flooding of the reservoir, organic carbon release from flooded soils exceeds CO2 emissions, implying the downstream export of large quantities of eroded soil organic carbon. After this initial period, CO2 emissions are fuelled by organic carbon originating from the drainage basin. 相似文献
78.
Natalia Moreno Mar Viana Marco Pandolfi Andrs Alastuey Xavier Querol Servando Chinchn Juan Francisco Pinto Federico Torres Juan Manuel Díez Jos Saz 《Journal of environmental management》2009,91(1):133-141
Remodelling works are frequent in harbour areas, given that they must adapt to rapidly changing market requirements. Depending on their nature (construction, demolition, etc.), these works may be carried out during long periods of time and thus exert a significant impact on the air quality at the harbours and their surroundings. The air quality at the Valencia harbour was studied during an enlargement project. Four sampling stations aimed to cover the major dust-emitting activities in the harbour. In addition, a sampling campaign was carried out to collect dust materials at their emission sources (e.g., loading and unloading of clinker and petroleum coke, as well as the enlargement works). Differences obtained between PM levels at the monitoring sites were correlated with the distance between sampling stations and enlargement works and/or harbour operations, as well as with the preferential wind direction. In all cases, the days with the highest PM_10 levels were linked to wind directions coinciding with the location of the enlargement works or the clinker and petroleum coke stocks. Classic source apportionment methodologies (PCA and CMB) were applied to the data, but their interpretation was complex due to the similar chemical signatures of PM originating from direct and fugitive emissions from stocked materials (e.g., clinker), and the enlargement works. To overcome this difficulty, a novel non-statistical approach was used to obtain quantitative estimations of the contributions from sources (petroleum coke and clinker), based on the correlation between specific PM components (e.g., carbonaceous species) and source tracers (e.g., V). Finally, a qualitative test using phenolphthalein was devised to identify the presence of clinker on the filters, which provided positive results. This novel tracer approach is thus recommended for harbour authorities. 相似文献
79.
Silvina Vargas Gil Analia Becker Claudio Oddino Mónica Zuza Adriana Marinelli Guillermo March 《Environmental management》2009,44(2):378-386
Soil microbial populations can fluctuate in response to environmental changes and, therefore, are often used as biological
indicators of soil quality. Soil chemical and physical parameters can also be used as indicators because they can vary in
response to different management strategies. A long-term field trial was conducted to study the effects of different tillage
systems (NT: no tillage, DH: disc harrow, and MP: moldboard plough), P fertilization (diammonium phosphate), and cattle grazing
(in terms of crop residue consumption) in maize (Zea mays L.), sunflower (Heliantus annuus L.), and soybean (Glycine max L.) on soil biological, chemical, and physical parameters. The field trial was conducted for four crop years (2000/2001,
2001/2002, 2002/2003, and 2003/2004). Soil populations of Actinomycetes, Trichoderma spp., and Gliocladium spp. were 49% higher under conservation tillage systems, in soil amended with diammonium phosphate (DAP) and not previously
grazed. Management practices also influenced soil chemical parameters, especially organic matter content and total N, which
were 10% and 55% higher under NT than under MP. Aggregate stability was 61% higher in NT than in MP, 15% higher in P-fertilized
soil, and also 9% higher in not grazed strips, bulk density being 12% lower in NT systems compared with MP. DAP application
and the absence of grazing also reduced bulk density (3%). Using conservation tillage systems, fertilizing crops with DAP,
and avoiding grazing contribute to soil health preservation and enhanced crop production. 相似文献
80.
基于可拓学石化装置失效后果严重度评估方法研究 总被引:1,自引:1,他引:0
石化企业中,石化装置的安全运行对保证企业的安全生产起到关键作用,其一旦失效发生事故,将导致巨大的人员伤亡及财产损失。因此,开展石化装置失效后果严重性的评价研究,对保证石化企业的安全生产具有重要意义。本文根据物元可拓性理论,结合石化装置失效后果的严重性情况,运用可拓评判方法建立石化装置失效后果严重度的综合评判模型,给出了评价步骤,最终确定设备失效后果的严重程度。研究结果表明,该方法可应用于多层次的工程风险评价问题,从而为石化工程项目风险管理提供了一种有效的分析方法。 相似文献